Short answer: tempered glass is heat-treated to be roughly four times stronger than regular glass, and when it does break, it shatters into small, blunt pieces instead of sharp shards — which is why it's required near doors, floors, and wet areas.
How it's made
The glass is heated to a high temperature and then rapidly cooled, creating internal stress that makes the outer surfaces compress and the interior stay in tension — this is what gives it both extra strength and its safe-breaking pattern.
Why it matters for your project
Anywhere a person could fall into or through glass, tempered (or laminated) glass is required by code precisely because the failure mode is so much safer than standard annealed glass.
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